;dipshift.mh ;2D CH-13C correlation, with homonuclear dec. during t1. ;Munowitz MG, Griffin RG, Bodenhausen G, Huang TH. ;J. Am. Chem. Soc., volume 103, 2529, 1981 ;p3: 1H excitation ;p15: CP contact ;p2: 13C 180 pulse ;d0: evolution period ;pl2: 1H hard power ;pl12: 1H power for decoupling ;pl3: 1H CP power ;pl1: 13C CP power ;pl22: 1H homo dec power ;pl23: MREV-8 power inside the cpd program ;pl11: 13C hard pulse power ;in0: t1 increment ;in10: t1 decrement "d10=1s/l31+in10" ;shrinking time "l1=aq/(p8*2)" ;1H TPPM decoupling 1 ze 10m dd10 ;to avoid last (-) time, use for 2D 2 d1 10u pl1:f1 10u pl2:f2 ;set decoupler power 2u:f2 ph1 2u:f1 ph2 ;--------------------- CP --------------------------- 3 p3:f2 ph1 ;1H excitation 0.5u pl3:f2 ;change 1H power for CP (p15 ph2):f1 (p15 ph3):f2 ;CP ;-------------- 1H homo dec for evolution ------------------- 1u pl22:f2 pl11:f1 ;set homo. decoupling power 4 1u cpds2:f2 ;homonuclear dec. d0 ;t1 0.5u do:f2 ;CW decoupling 0.5u cw:f2 pl12:f2 d10:f1 ph8 ;shrinking time p2:f1 ph8 ;13C 180, iso shift refocusing d0 ;second tr 1u d10 1u:f1 ph0 ;dead time delay, reset RF phase to detect 1u adc ph31 ;start ADC with ph31 signal routing 5 p8:f2 ph13 p8:f2 ph14 lo to 5 times l1 aq do:f2 rcyc=2 ; wr #0 ;2D 100m wr #0 if #0 zd ;write file to disk, increment, zero data 10m id0 lo to 1 times td1 exit ph0= +x ph1= +x -x ;1H excitation ph2= +x +x +y +y -x -x -y -y ;13C CP ph3= +y ;1H CP ph8= +x +x +y +y -x -x -y -y ;13C 180 pulse +y +y -x -x -y -y +x +x ph13= (360) 10 ph14= (360) 0 ph31= 0 2 1 3 2 0 3 1 ;acquisition 2 0 3 1 0 2 1 3